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Lithium tri-tert-butoxyaluminum hydride (TBLAH)

Lithium tri-tert-butoxyaluminum hydride is less reactive than lithium aluminum hydride (LAH) and is very useful in selective reductions of acyl halides, aldehydes, ketones, and esters. This reagent generally shows increased solubility, particularly at low temperatures in organic solvents. For reviews see: 1) H.C. Brown; J.Am.Chem.Soc. 1964, 86, 1089; 2) J. Malek; M. Cerny, Synthesis, 1972, 217; and 3) J. Malek, Org. React. 1985, 34,1.

CAS #: 17476-04-9

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